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3.3 GDP-D-mannose pyrophosphorylase (GMP: EC 2.7.7.13) In a relatively short period of time after the discovery of the L-galactose pathway for AsA biosynthesis in plants (Wheeler et al., 1998), several of their genes encoding enzymes (including the VTC1 gene) were identified in mutant plants isolated from a collection of AsA-deficient thale cress mutants
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